Xavi made a record 143rd appearance in the Champions League when he came on as a substitute in the second half of Tuesday's Group F match at PSG.
Xavi currently shares the appearance record of 142 Champions League matches with former Real Madrid and Schalke 04 striker Raul.
Luiz and midfielder Marco Verratti scored their first goals for Paris Saint-Germain in a 3-2 win over Barcelona.
Zlatan Ibrahimovic is out for the match against Barcelona, and Paris Saint-Germain must find a way to cope without him.
Paris Saint-Germain have even more reason to fear Barcelona star Lionel Messi when the teams meet in the Champions League on Tuesday.
Barcelona led by their lethal attacking duo of Lionel Messi and Neymar, will be confident of picking up a second straight win to take control of Group F.
Douglas, who Barcelona acquired from Sao Paulo on a five-year contract, made a poor debut for the Spanish league leaders in their 0-0 draw against Malaga.
Neymar and Messi ran riot as Barcelona maintained their perfect start to the season with a stunning 6-0 demolition of Granada at Camp Nou.
Barcelona coach Luis Enrique has given his backing to Xavi and says the veteran midfielder remains a valuable member of the squad.
Vermaelen has recovered from a right leg injury that has kept him from debuting with his new club since transferring from Arsenal.
Lionel Messi failed to take his chances as Barcelona were held to a 0-0 draw by a disciplined and defensive Malaga side in the Spanish league on Wednesday.